Dyes removal from water using low cost absorbents

In this study, the removal capacity of low cost adsorbents during the adsorption of Methylene Blue (MB) and Congo Red (CR) at different concentrations (50 and 100mg•L-1) was evaluated. These adsorbents were produced from wood wastes (cedar and teak) by chemical activation (ZnCl2). Both studied materials, Activated Cedar (AC) and activated teak (AT) showed a good fit of their experimental data to the pseudo second order kinetic model and Langmuir isotherms. The maximum adsorption capacities for AC were 2000.0 and 444.4mg•g-1 for MB and CR, respectively, while for AT, maximum adsorption capacities of 1052.6 and 86.4mg•g-1 were found for MB and CR, respectively. © Published under licence by IOP Publishing Ltd

Spin nematics and magnetization plateau transition in anisotropic Kagome magnets

We study S=1 kagome antiferromagnets with isotropic Heisenberg exchange $J$ and strong easy axis single-ion anisotropy $D$. For $D \gg J$, the low-energy physics can be described by an effective $S=1/2$ $XXZ$ model with antiferromagnetic $J_z \sim J$ and ferromagnetic $J_\perp \sim J^2/D$. Exploiting this connection, we argue that non-trivial ordering into a "spin-nematic" occurs whenever $D$ dominates over $J$, and discuss its experimental signatures. We also study a magnetic field induced transition to a magnetization plateau state at magnetization 1/3 which breaks lattice translation symmetry due to ordering of the $S^z$ and occupies a lobe in the $B/J_z$-$J_z/J_\perp$ phase diagram.Comment: 4pages, two-column format, three .eps figure

Semiclassical ordering in the large-N pyrochlore antiferromagnet

We study the semiclassical limit of the $Sp(N)$ generalization of the pyrochlore lattice Heisenberg antiferromagnet by expanding about the $N \to \infty$ saddlepoint in powers of a generalized inverse spin. To leading order, we write down an effective Hamiltonian as a series in loops on the lattice. Using this as a formula for calculating the energy of any classical ground state, we perform Monte-Carlo simulations and find a unique collinear ground state. This state is not a ground state of linear spin-wave theory, and can therefore not be a physical (N=1) semiclassical ground state.Comment: 4 pages, 4 eps figures; published versio

The symmetry of the spin Hamiltonian in herbertsmithite, a spin-1/2 kagom\'{e} lattice

We present magnetization measurements on oriented powder of ZnCu$_{3}$(OH)$_{6}$Cl$_{2}$ along and perpendicular to the orienting field. We find a dramatic difference in the magnetization between the two directions. It is biggest at low measurement fields $H$ or high temperatures. We show that the difference at high temperatures must emerge from Ising-like exchange anisotropy. This allows us to explain muon spin rotation data at $T\to 0$ in terms of an exotic ferromagnetic ground state.Comment: 5 pages, 5 figure

The effect of the lateral interactions on the critical behavior of long straight rigid rods on two-dimensional lattices

Using Monte Carlo simulations and finite-size scaling analysis, the critical behavior of attractive rigid rods of length k (k-mers) on square lattices at intermediate density has been studied. A nematic phase, characterized by a big domain of parallel k-mers, was found. This ordered phase is separated from the isotropic state by a continuous transition occurring at a intermediate density \theta_c, which increases linearly with the magnitude of the lateral interactions.Comment: 7 pages, 6 figure

Perturbative evolution of the static configurations, quasinormal modes and quasi normal ringing in the Apostolatos - Thorne cylindrical shell model

We study the perturbative evolution of the static configurations, quasinormal modes and quasi normal ringing in the Apostolatos - Thorne cylindrical shell model. We consider first an expansion in harmonic modes and show that it provides a complete solution for the characteristic value problem for the finite perturbations of a static configuration. As a consequence of this completeness we obtain a proof of the stability of static solutions under this type of perturbations. The explicit expression for the mode expansion are then used to obtain numerical values for some of the quasi normal mode complex frequencies. Some examples involving the numerical evaluation of the integral mode expansions are described and analyzed, and the quasi normal ringing displayed by the solutions is found to be in agreement with quasi normal modes found previously. Going back to the full relativistic equations of motion we find their general linear form by expanding to first order about a static solution. We then show that the resulting set of coupled ordinary and partial differential equations for the dynamical variables of the system can be used to set an initial plus boundary values problem, and prove that there is an associated positive definite constant of the motion that puts absolute bounds on the dynamic variables of the system, establishing the stability of the motion of the shell under arbitrary, finite perturbations. We also show that the problem can be solved numerically, and provide some explicit examples that display the complete agreement between the purely numerical evolution and that obtained using the mode expansion, in particular regarding the quasi normal ringing that results in the evolution of the system. We also discuss the relation of the present work to some recent results on the same model that have appeared in the literature.Comment: 27 pages, 7 figure